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ATPase, (114) potentiate the toxicity of paraquat,(136) and mediate
lipid peroxidation.(1l4) They may also contribute to the
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pathophysiology of disorders of purine metabolism. (24,26,137,138).
The exact mix of pro or antioxidant properties for a particular
reducing agent is a complex integration of several factors. In the
case of hydroxyl radical scavengers,.as is the case with
glutathione and superoxide. Similarly, pH greatly influences the
direct reduction of oxygen to superoxide by sulfhydryl compounds,
(107) while other local factors such as the molar concentration of
oxygen molecules are also important.
. As is the case with reducing
antioxidants, such compounds may also produce active electronic
species (45,73-79,118) and perhaps disease.
TABLE III. Antioxidant
defense - chemicals (modified after refs. 17-19)
Ascorbate
Tocopherols